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In this study, the non-primitive mean spherical approximation (NPMSA) model has been modified and an equation
is obtained for calculating the cationic diameter for single electrolyte solutions at various concentrations.
Furthermore, based on this modification of the NPMSA model an equation for the Helmholtz energy is derived
and the thermodynamic properties are calculated at various ionic strengths and dipole diameters. The results
show that the pair potential and electrostatic forces play the main role in the obtained thermodynamic
properties.
Also, the calculated thermodynamic properties by theNPMSAmodel are compared with results from other models
such as primitive mean spherical approximation (PMSA) and restricted mean spherical approximation (RMSA).
The results indicate that the NPMSA model underestimates the thermodynamic properties due to the solvent effects
in this model.
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The paper of electrolyte modelling from Mr. Morteza Lotfikian is very useful for future fundamental research works in electrolyte solutions. I read this paper and found some new veiws in it. My co works accepted my view too.
Posted by: mike | December 27, 2005 at 12:58 PM
excellent!!!
I think this work could be pursue to many other fields.
Posted by: babak khan | January 07, 2008 at 08:12 AM
Hi,
Good article.The InterNanotech Community of Practice in computational and experimental nanotechnology has launched at the Pacific Rim Conference in Nanoscience, Broome, Australia.
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